含黑色草花状包裹体的南红玛瑙的宝石学特征

Mineralogical Characteristic of Nanhong Agate with Black Seaweed Pattern Mineral Inclusion

  • 摘要: 四川凉山产出一类同时含红色和黑色球粒状矿物包裹体的南红玛瑙,其包裹体常以丝脉状、浸染状聚集构成独特的草花状图案。采用红外光谱、X射线粉末衍射及拉曼光谱等测试方法,得知该类南红玛瑙主要矿物组成为石英,斜硅石含量低,结晶度指数6.76;红外透射光谱3 674 cm-1处的吸收峰及X射线粉末衍射中d=8.418 Å衍射弱峰推测层状硅酸盐矿物存在; 红色球粒状矿物具226、245、292 cm-1等赤铁矿拉曼特征位移峰; 黑色球粒状矿物显示金属硫化物拉曼特征位移峰,多分布在342 cm-1和377 cm-1附近,结合扫描电子显微镜的能谱(EPS)分析及电子背散射衍射(EBSD)测试确定黑色球粒状矿物为立方晶系黄铁矿(FeAs(0.015-0.018 5)S(1.826-1.886),与少量黄铜矿(拉曼特征位移峰289 cm-1)共生; 此类南红玛瑙中黑色球粒状矿物的组成、形态分布明显区分于其他地区玛瑙中常见构成草花状图案的铁锰质、有机质等黑色包裹体,有一定产地指示意义。

     

    Abstract: Nanhong agate from Liangshan Yi Autonomous Prefecture of Sichuan Province, China has gained great popularity in the gem market in China for its vibrant colour. Its attractive orange-red colour is generated by fine hematite concentrations. Recently, a new kind of agate named "black seaweed pattern agate", belonging to the family of the Nanhong agates appeared in the local market of Liangshan Prefecture. Microscopic examination showed that the fine red and black grain minerals scattered in various forms such as silkiness and disseminated forms in the sample. Infrared spectrometer, Raman spectrometer and X-ray powder diffraction were used to study the gemmological and mineralogical characteristics of the agate. The results proved that the main mineral component of the agate was quartz with a low relative content of moganite and high degree of order. The crystallinity of the agate is about 6.76. FTIR spectra showed a weak peak at 3 674 cm-1 related to OH-. Combined with the XRD testing result (d=8.418 Å), it supported the existence of phyllosilicates in the agate. Raman spectrum of red grain mineal showed peaks at 226, 245, 292 cm-1, which matched well with hematite. Meanwhile the spectrum of black grain was consistent with sulfide minerals (peaks at 342, 377 cm-1). Further testing results of scanning electron microscopy and back scattering diffraction confirmed that most of the black grain mineral is pyrite(FeAs(0.015-0.018 5)S(1.826-1.886)), which belongs to isometric system. According to Raman database, the last peak at 289 cm-1 was identical with chalcopyrite. All these evidence showed pyrite had a paragenetic relationship with chalcopyrite in some area of "black seaweed pattern agate". Another important features were that mineral components and morphological distribution of these black grains were obviously different from features such as Fe and Mn oxides and organic grains that appear in common seaweed pattern agate from other places, which may indicate that the origin of "black seaweed pattern agate" is from Liangshan.

     

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