绿柱石热处理前后内部显微特征对比研究

Comparison of the Microscopic Characteristics of Beryl before and after Heat Treatment

  • 摘要: 绿柱石的热处理工艺简单、应用广泛,且经热处理后其颜色稳定,因此市场上常出现经热处理的绿柱石如海蓝宝石。经热处理后绿柱石的内部显微特征可能会发生一定变化。采用马弗炉在空气条件下进行400~1 000 ℃范围内热处理实验,通过运用显微拍照记录样品热处理前后内部显微特征以及激光拉曼光谱仪测试样品热处理前后气液包裹体成分。研究结果表明,未经热处理绿柱石内部存在以CO2+N2+CH4为混合气体和溶有少量CO2的H2O为液体的气液两相包裹体;热处理后绿柱石部分气液包裹体会发生爆裂,导致流体逸出,只剩下空腔。此外,包裹体爆裂后导致其原有形状发生一定的变化,主要表现为部分扁平状气液两相包裹体变为扁平状裂隙,拉长管状气液包裹体腔壁出现局部断裂和收缩。流体包裹体爆裂与热处理温度、包裹体大小有关。当热处理温度为400 ℃时,绿柱石中仅部分较大尺寸的气液包裹体中气液逸出;当热处理温度大于或等于650 ℃时,几乎所有的气液包裹体中气液均逸出。对发生爆裂的流体包裹体的拉曼测试,未检测到原来的气相和液相的拉曼位移峰,进一步证实了热处理后空腔包裹体的形成。通过显微观察绿柱石内部气液包裹体特征是鉴别其是否经过热处理的有效手段,较小尺寸气液包裹体的变化特征或可指示热处理温度,系统地研究绿柱石热处理前后内部显微特征,有助于热处理绿柱石的有效鉴别。

     

    Abstract: The thermal treatment process of beryl is quite simple, and this method is widely applied for colour modification of beryl. The colour of heat-treated beryl is stable, and heat-treated beryl, such as aquamarine, is comparatively common in the market. The internal microscopic features of beryl may change somewhat after heat treatment. A muffle furnace was used for heat treatment experiments in the range of 400~1 000 ℃ under air conditions. Microscopic photographs were used to record the microscopic characteristics of the samples before and after heat treatment; laser Raman spectrometer was also applied to determine the potential composition changes of gas-liquid inclusions. The natural beryl was characterized by gas-liquid inclusions with CO2+N2+CH4 as the gas composition and H2O with a small amount of dissolved CO2 as the liquid phase composition. The results showed that after heat treatment, some of the gas-liquid inclusions burst, causing the fluid to escape and leaving only the cavity. In addition, the burst inclusions lead to some changes in their original shape, mainly manifested as part of the flattened gas-liquid two-phase inclusions changes into flattened fractures, elongated tubular gas-liquid inclusion cavity walls appear local fracture and shrinkage. Fluid inclusions burst is related to the heat treatment temperature and inclusion size. When the heat treatment temperature is 400 ℃, burst was only observed in gas-liquid inclusions of relative larger size in beryl. In contrast, when the heat treatment temperature is equal or higher than 650 ℃, almost all the gas-liquid inclusions burst. Raman analysis did not detect the Raman peaks of the initially captured gas and liquid compositions in the bursted fluid inclusions, further confirms the formation of inclusion cavity after heat treatment. Microscopic observation of gas-liquid inclusions in beryl is an effective means to identify whether it has been heat-treated or not. The variation of gas-liquid inclusions of smaller sizes may indicate the heat treatment temperature. The systematic study of the internal microscopic features of beryl before and after heat treatment may contribute to the effective identification of heat-treated beryl.

     

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