染色透闪石玉仿墨玉的宝石学特征及其鉴定方法研究

Gemmological Characteristic and Identification Method of Dyed Tremolite Imitating Natural Black Tremolite Jade (Mo Yu)

  • 摘要: 采用拉曼光谱、紫外-可见光谱、红外光谱、X射线荧光光谱、激光剥蚀电感耦合等离子体质谱等现代测试方法,对市面上销售的称之为“墨玉”的黑色玉石与贵州罗甸透闪石玉、广西大化透闪石玉以及新疆墨玉进行了对比研究。结果表明,此种黑色透闪石玉样品经过了染色处理以仿制天然墨玉。通过与天然透闪石玉样品的对比研究,染色处理透闪石玉样品的透明度较低,部分样品横截面可见颜色分带,长波紫外光下呈特殊荧光现象,部分样品具有水草状花纹。拉曼光谱证实其主要成分为透闪石,在处理部位可见团块状、浸染状及不规则条带状石墨的1 580 cm-1振动;紫外-可见吸收光谱则表明,天然透闪石玉样品具有270 nm和950 nm附近的吸收峰,而染色样品则无该吸收;红外光谱表明染色部位中的结构水占比减少。XRF及LA-ICP-MS测试表明染色透闪石玉样品与广西大化透闪石玉具有相似的化学成分,二者均具有较高的Mn含量及相似的稀土元素配分模式。根据染色透闪石玉样品颜色观察、成分、拉曼光谱等特征,结合笔者对大化及罗甸透闪石玉染色处理实验结果,基本确定本文研究染色样品为大化透闪石玉经糖酸处理产物。

     

    Abstract: In this study, Raman spectroscopy, UV-Vis spectroscopy, Infrared spectroscopy, X-ray fluorescence spectroscopy, laser ablation inductively coupled plasma mass spectrometry and other modern testing methods were used to compare the "Mo Yu" called by the sellers on the market with tremolite from Luodian, Guizhou and Dahua, Guangxi, and Mo Yu from Xinjiang. The results show that this kind of "Mo Yu" called by the sellers is dyed to imitate natural black tremolite. Compared with natural tremolite jade, it is found that this kind of dyed tremolite is mostly subtranslucent or opaque, and colour zonation can be found on the cross section of some samples. Under the long-wave ultraviolet light, special fluorescence phenomena can be observed, and some samples show the pattern of water plants. Raman spectra confirm that the main component of the sample is tremolite, 1 580 cm-1 vibration of lumpy, disseminated, and irregular banded graphite can be seen at the treated site. Ultraviolet-visible absorption spectra show that natural tremolite jade samples have absorption peaks near 270 nm and 950 nm, which is unobservable with dyed tremolite jade samples. The infrared spectrum show that the content of constitution water in dyed part decreased, its integral area of the infrared spectrum is reduced about 2.6%. XRF and LA-ICP-MS tests show that the dyed tremolite jade samples have similar chemical compositions with tremolite jade from Dahua, Guangxi, both of which have high Mn content and similar distribution patterns of rare earth elements. According to the colour observation, composition, Raman spectra, and other characteristics of the dyed tremolite jade samples, combined with the authors' experimental results on tremolite from Dahua and Luodian, it is basically determined that the dyed tremolite jade samples in this study are the products of Dahua tremolite treated with sugar and acid.

     

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